Black Damp
Black-damp is also known as choke-damp
or stythe, and is a mixture of nitrogen and oxygen
in proportion varying from 5 to 20 % of carbon dioxide.
With 5 % carbon
dioxide it is about as heavy as air but increases
in density according to the percentage of carbon
dioxide.
It is not a poisonous gas except in proportions
which would cause death by suffocation in a short
time.
The properties of the gas vary with its composition,
but they are approximately indicated where the combined
effects of carbon dioxide and a shortage of oxygen
are tabulated; the presence of black-damp would
produce a somewhat similar atmosphere and therefore
similar effect.
The gas occurs in old workings, badly ventilated
dip workings, and in the coal and adjacent strata.
As a rule it tends to accumulate on the floor, but
this depends upon the percentage of the heavier
carbon dioxide.<
Black-damp may be regarded as the residual nitrogen
of the air mixed with carbon dioxide which has taken
the place of oxygen due to oxidation, decay, etc.
Though the whole of the oxygen may have been absorbed,
only part of it is, as a rule, replaced by carbon
dioxide, since some of the oxygen remains occluded
in the coal. Therefore black-damp will normally
contain more nitrogen than ordinary air.
The following is a representative sample of return
air
|
Oxygen
|
20.34%
|
|
Nitrogen
|
78.768%
|
|
Methane
|
0.5%
|
|
Carbon dioxide
|
0.392%
|
| |
100.000%
|
|
This corresponds to 97% pure
air, 0.5 %, methane, and 2.5 % black-damp, as indicated
below
|
Oxygen
|
20.34%
|
97.0% air |
|
Nitrogen
|
76.63%
|
|
Carbon dioxide
|
0.03%
|
|
Methane
|
0.5%
|
0.5% methane
|
|
Nitrogen
|
2.0138%
|
2.5%
black-damp |
|
Carbon dioxide
|
0.362%
|
|
In this sample black-damp contains
14.5 %. carbon dioxide,
but we may regard 13 % as the average carbon dioxide
content of black-damp. About 15 to 19 %, of the gas
will extinguish lights.
|