Black-damp is also known as choke-damp or stythe, and is
a mixture of nitrogen and oxygen in proportion varying from
5 to 20 % of carbon dioxide.
With 5 % carbon dioxide it is about as heavy as air but
increases in density according to the percentage of carbon
dioxide.
It is not a poisonous gas except in proportions which would
cause death by suffocation in a short time.
The properties of the gas vary with its composition, but
they are approximately indicated where the combined effects
of carbon dioxide and a shortage of oxygen are tabulated;
the presence of black-damp would produce a somewhat similar
atmosphere and therefore similar effect.
The gas occurs in old workings, badly ventilated dip
workings, and in the coal and adjacent strata. As a rule it
tends to accumulate on the floor, but this depends upon the
percentage of the heavier carbon dioxide.<
Black-damp may be regarded as the residual nitrogen of the
air mixed with carbon dioxide which has taken the place of
oxygen due to oxidation, decay, etc. Though the whole of the
oxygen may have been absorbed, only part of it is, as a
rule, replaced by carbon dioxide, since some of the oxygen
remains occluded in the coal. Therefore black-damp will
normally contain more nitrogen than ordinary air.
The following is a representative sample of return air
Oxygen
20.34%
Nitrogen
78.768%
Methane
0.5%
Carbon dioxide
0.392%
100.000%
This corresponds to 97% pure air, 0.5 %, methane, and 2.5
% black-damp, as indicated below
Oxygen
20.34%
97.0% air
Nitrogen
76.63%
Carbon dioxide
0.03%
Methane
0.5%
0.5% methane
Nitrogen
2.0138%
2.5% black-damp
Carbon dioxide
0.362%
In this sample black-damp contains 14.5 %. carbon
dioxide, but we may regard 13 % as the average carbon
dioxide content of black-damp. About 15 to 19 %, of the gas
will extinguish lights.